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KRS6 Thallium Bromo-Chloride

KRS6 Thallium Bromo-Iodide Data SheetDownload
KRS6 Thallium Bromo-Iodide SDSDownload

KRS-6 has few applications. Occasionally, it is required for research purposes.

Transmission Range 0.4 to 25 μm
Refractive Index 2.1723 at 11 μm (1)
Reflection Loss 24% at 11 μm (2 surfaces)
Absorption Coefficient n/a
Reststrahlen Peak 91.5 μm
dn/dT n/a
dn/dμ = 0 5 μm
Density 7.18 g/cc (3)
Melting Point 423°C
Thermal Conductivity 0.7 W m-1 K-1 @ 329 K
Thermal Expansion 50 x 10-6 K-1 (2)
Hardness Knoop 29.9 with 500g indenter (2)
Specific Heat Capacity 188 J Kg-1 K-1
Dielectric Constant 32 at 1 MHz
Youngs Modulus (E) 20.68 GPa (2)
Shear Modulus (G) 8.48 GPa (2)
Bulk Modulus (K) 22.81 GPa (2)
Elastic Coefficients C11 = 38.5; C12 = 14.9; C44 = 7.37
Apparent Elastic Limit 20.7 MPa (3000psi)
Poisson Ratio 0.219
Solubility 0.3g/100g water at 20°C
Molecular Weight 40 mole% TlBr; 60 mole% TlCl
Class/Structure Cubic, CsCl structure, Pm3m, no cleavage (3)

μmNo
0.62.3294
0.72.2982
0.82.2660
0.92.2351
1.02.2048
1.52.2148
2.02.2059
3.02.1956
4.02.1956
5.02.1928
7.02.1887
9.02.1885
10.02.1767
11.02.1722
12.02.1674
13.02.1624
14.02.1563
15.02.1504
16.02.1442
17.02.1377
18.02.1309
19.02.1236
20.02.1154
21.02.1067
22.02.0976
23.02.0896
24.02.0752

KRS-6 crystals are grown by the sealed-ampoule Stockbarger technique. Starting materials of the highest purity are selected to ensure that there are no anionic absorption bands between 2 and 16 microns and all crystals are checked for quality by using a pathlength of 120mm. Thallium salts are toxic, and KRS6 has enough solubility to require extreme caution. Careful handling with plastic gloves covered with soft cotton gloves as appropriate to delicate optics is required.

REFERENCES:
(1) Hettner and Leisegang; Optik, V3, p305, 1948
(2) Combes, Ballard, McCarthy: J.Opt Soc.Am. V41, p 215, 1951
(3) Handbook of Optical Constants, ed Palik, V3, ISBN 0-12-544423-0

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