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Strontium Fluoride SrF2

Strontium Fluoride (SrF2) SDSDownload
Strontium Fluoride (SrF2) Data SheetDownload

Strontium Fluoride has only specialist applications. Optically, Strontium Fluoride has properties intermediate to Calcium and Barium Fluoride.

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Transmission Range 0.15 to 11 μm
Refractive Index 1.439 at 0.55 μm (1)
Reflection Loss 6.3% at 0.55 μm (2 surfaces)
Absorption Coefficient <1 x 10-3 cm-1 @ 5 μm
Reststrahlen Peak 46 μm
dn/dT -12 x 10-6 K-1
dn/dμ n/a
Density 4.24 g/cc
Melting Point 1450°C
Thermal Conductivity 8.3 W m-1 K-1 @ 293 K (2)
Thermal Expansion 18.4 x 10-6/°C @ 293 K
Hardness Knoop 154 (100) & 140 (110)
Specific Heat Capacity 543 J Kg-1 K-1
Dielectric Constant 7.69 at 2 MHz
Young's Modulus (E) 89.1 GPa
Shear Modulus (G) 34.6 GPa
Bulk Modulus (K) 24.65 GPa
Elastic Coefficients C11 = 124; C12 = 45; C44 = 31.7
Apparent Elastic Limit 36.5 MPa (5300 psi)
Poisson Ratio 0.25
Solubility 0.012 g/100 g water at 27°C
Molecular Weight 125.62
Class/Structure Cubic Fm3m (#225), cleaves on (111)
μmNoμmNoμmNo
0.151.5940.911.433437.011.37308
0.201.5041.011.432698.011.35362
0.311.457251.511.430038.101.3517
0.411.445562.011.427618.601.3405
0.511.440293.011.421599.101.3283
0.611.437404.011.413379.601.3151
0.711.435605.011.4026910.61.2854
0.811.434356.011.3893411.11.2686

Strontium fluoride is produced by the vacuum Stockbarger growth technique.

REFERENCES:
(1) Handbook of Optical Constants, ed Palik, V3, ISBN 0-12-544423-0

(2) For Thermal Conductivity (Tc) a figure of 1.42 W/(mK) is in wide circuation but is plainly incorrect based on observation of UKRI STFC (2019) plus logically the Tc should be intermediate between BaF2 and CaF2.  OSTI.GOV  gives (p44) 0.016 cal cm-1 s C-1 for 25°C which converts to 6.7 W m-1 K-1. OSA PUBLISHING confirms (p95) our existing Tc for CaF2 as 9.71W m-1K-1 and offers for SrF2 as 8.3 W m-1 K-1

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